Surface Ba species effective for photoassisted NOx storage over Ba-modified TiO2 photocatalysts
기관명 | NDSL |
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저널명 | Applied catalysis. B, Environmental |
ISSN | 0926-3373,1873-3883 |
ISBN |
저자(한글) | Yamamoto, A.,Mizuno, Y.,Teramura, K.,Hosokawa, S.,Tanaka, T. |
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저자(영문) | |
소속기관 | |
소속기관(영문) | |
출판인 | |
간행물 번호 | |
발행연도 | 2016-01-01 |
초록 | Surface modification of a TiO 2 photocatalyst with Ba species was investigated in photoassisted nitrogen oxide (NO x ) storage under UV-light irradiation. The NO x storage capacity in the Ba-modified TiO 2 photocatalyst was 1.4 times higher than that of the non-modified TiO 2 photocatalyst. Structure and role of the surface Ba species on a TiO 2 surface were characterized using temperature programmed reaction (TPR), diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), and transmission electron microscopy (TEM). The characterization results suggested that Ba-Ti mixed oxides with a two-dimensional layer and amorphous structure on a TiO 2 surface were generated via decomposition of Ba(NO 3 ) 2 precursors by O 2 pretreatment at 773K. Based on the results of the characterizations and the reactions, the generated Ba-Ti mixed oxides on a TiO 2 surface stored NO x more densely than the TiO 2 surface; therefore, the generation improved the activity in the photoassisted NO x storage under UV-light irradiation. |
원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=NART73035790 |
첨부파일 |
과학기술표준분류 | |
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ICT 기술분류 | |
DDC 분류 | |
주제어 (키워드) | Photocatalyst,Nitrogen oxides,NO lt,SUB gt,x lt,/SUB gt,. Titanium dioxide,NO lt,SUB gt,x lt,/SUB gt,storage |