Surface-initiated polymerization of styrene from one-step prepared thiol-functionalized organoclays
기관명 | NDSL |
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저널명 | Polyhedron |
ISSN | 0277-5387,1873-3719 |
ISBN |
저자(한글) | Survant, L.,Andrejevic, M.,Picker, J.,Van Den Hoek, J.,Fossum, E.,Lagadic, I. |
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저자(영문) | |
소속기관 | |
소속기관(영문) | |
출판인 | |
간행물 번호 | |
발행연도 | 2016-01-01 |
초록 | A polystyrene-organoclay composite material was prepared by surface-initiated radical polymerization of styrene from the surface of thiol-functionalized organoclays synthesized in a one-step process. Characterizations of the composite by infrared spectroscopy (FTIR) and powder X-ray diffraction (PXRD) confirmed a direct covalent bonding between the polystyrene and the clay layers and an essentially exfoliated structure. The significant amount of SH reactive sites present in the organoclay resulted in a high grafting percentage (PG%, 49.8%) and in a high content of grafted polystyrene in the material (35.8wt%), indicating that such polystyrene-grafted organoclays could be easily used as polymer fillers for incorporation in various polymeric matrices. |
원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=NART75761940 |
첨부파일 |
과학기술표준분류 | |
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ICT 기술분류 | |
DDC 분류 | |
주제어 (키워드) | Tethered polystyrene,Organoclays,Thiol-functionalized,Polystyrene-clay nanocomposites,Surface-initiated polymerization |