저자(한글) |
Hussain, S.,Liu, T.,Javed, M.S.,Aslam, N.,Shaheen, N.,Zhao, S.,Zeng, W.,Wang, J. |
초록 |
Low-cost dynamic materials for Faradaic redox reactions are needed for high-energy storage supercapacitors. A simple and cost-effective hydrothermal process was employed to synthesize amaryllis-like NiCo 2 S 4 nanoflowers. The sample was characterized by X-ray powder diffraction, Brunauer-Emmett-Teller method, scanning electron microscopy, and transmission electron microscopy. NiCo 2 S 4 nanoflowers were coated onto carbon fiber fabric and used as a binder-free electrode to fabricate a solid-state supercapacitor compact device. The solid-state supercapacitor exhibited excellent electrochemical performance, including high specific capacitance of 360Fg -1 at scan rate of 5mVs -1 and high energy density of 25Whkg -1 at power density of 168Wkg -1 . In addition, the supercapacitor possessed high flexibility and good stability by retaining 90% capacitance after 5000 cycles. The high conductivity and Faradic-redox activity of NiCo 2 S 4 nanoflowers resulted in high specific energy and power. Thus, NiCo 2 S 4 nanoflowers are promising pseudocapacitive materials for low-cost and lightweight solid-state supercapacitors. |