| 초록 |
Nano plates of two Cd(II)-based metal-organic frameworks, [Cd 2 (oba) 2 (4-bpdb) 2 ] n .(DMF) x (TMU-8) and [Cd(oba)(4,4'-bipy)] n .(DMF) y (TMU-9) were synthesized via sonochemical reaction by using various time and concentrations of initial reagents and power of irradiation and characterized by scanning electron microscopy, X-ray powder diffraction and IR spectroscopy. Moreover, the effect of triethylamine on speed of nucleation during the synthesis was investigated. Thermolysis of these MOFs at 550 o C under air atmosphere yields CdO nanoparticles. |
