Quantitative Comparison of the Photocatalytic Efficiency of TiO2 Nanotube Film and TiO2 Powder
기관명 | NDSL |
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저널명 | 지하수토양환경 = Journal of soil and groundwater environment |
ISSN | 1598-6438, |
ISBN |
저자(한글) | Jang, Jun-Won,Park, Sung Jik,Park, Jae-Woo |
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저자(영문) | |
소속기관 | |
소속기관(영문) | |
출판인 | |
간행물 번호 | |
발행연도 | 2016-01-01 |
초록 | We compared the plausible reaction mechanism and quantitative efficiency of highly self-organized TiO 2 nanotube (ntTiO 2 ) film with TiO 2 powder. Film was fabricated by electrochemical potentiostatic anodization of titanium thin film in an ethylene-glycol electrolyte solution containing 0.3 wt% NH 4 F and 2 vol% deionized water. Nanotubes with a pore size of 80-100 nm were formed by anodization at 60 V for 3 h. Humic acid (HA) was degraded through photocatalytic degradation using the ntTiO 2 film. Pseudo first-order rate constants for 0.3 g of ntTiO 2 , 0.3 g TiO 2 powder, and 1 g TiO 2 powder were 0.081 min #x2212;1 , 0.003 min #x2212;1 , and 0.044 min #x2212;1 , respectively. HA adsorption on the ntTiO 2 film was minimal while adsorption on the TiO 2 powder was about 20% based on thermogravimetric analysis. Approximately five-fold more normalized OH radicals were generated by the ntTiO 2 film than the TiO 2 powder. These quantitative findings explain why ntTiO 2 film showed superior photocatalytic performance to TiO 2 powder. |
원문URL | http://click.ndsl.kr/servlet/OpenAPIDetailView?keyValue=03553784&target=NART&cn=JAKO201614859317499 |
첨부파일 |
과학기술표준분류 | |
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ICT 기술분류 | |
DDC 분류 | |
주제어 (키워드) | TiO lt,SUB gt,2 lt,/SUB gt,nanotubes,Electrostatic anodization,Humic acid,Adsorption effect,Terephthalic acid |